Showing posts with label nitrate. Show all posts
Showing posts with label nitrate. Show all posts

Tuesday, September 1, 2009

Effect of Urbanization on Ground water in Ranchi city, India.

Ranchi people needs 33858160 liters of water per day.
by
Dr. Nitish Priyadarshi



Ranchi the capital city of Jharkhand state of India is located at 23.350 N and 85.330 E. The total area covered by Ranchi-Municipal area is about 141 square kilometers and the average elevation of the city is 645 m above Mean Sea Level (MSL). As of 2001 India census Ranchi had a population of 846,454.

Water supply, in adequate quantity and at desirable quality, is essential for any sustainable urbanization. Water supply in Ranchi dates back to more than 50 years ago.

There are three main dams ( Hatia, Rukka, and Kanke dam) from where the water is supplied to the city. Surface water is always vulnerable to pollution. People of Ranchi are dependent more on purer source like groundwater. Of the total consumption more than 60% comes from groundwater storage. Due to increasing population more pressure has developed on groundwater from the aquifer beneath the city.

The process of urbanization and industrialization from last 20 years has caused changes in the water table as a result of decreased recharge and increased withdrawal. Many of the small ponds which were main source of water in the surrounding areas are now filled for different construction purpose affecting the water table. Lots of DEEP- BORING in the Ranchi city has also forced the water table to move down as well as Ranchi plateau

Large scale abstractions always bring changes in the natural system of the aquifer and also in the environment. Over exploitation of groundwater beneath some large cities of the world has resulted in serious environmental hazards like groundwater quality deterioration.

The International Conference on Water and Environment, Dublin, 1992 enunciated two crucially important guideline principles, namely, that all human beings have a basic right to access to clean water and sanitation at an affordable price, and that water has an economic value in all its competing uses and should be recognized as economic good.

Groundwater in Ranchi city:

Groundwater in Ranchi city is mainly stored here in secondary porosity features or void spaces developed as result of weathering, fracturing, jointing, shearing or faulting phenomena. The gneisses and granitic rocks with associated schists and quartzites constitute the main consolidated rock terrain of Ranchi district.

Major portion of Ranchi city which is part of the Chotanagpur Plateau occupied by hard rock which are devoid of primary porosity and occurrence and movement of groundwater is controlled by the joints, fractures and fissures present in them.

During the long span of geological history these rocks have been deformed and tectonised in many ways including deep erosion.

In Ranchi city water table in the consolidated formations is now at its lowest from April to June. Water table is at its highest peak during August, gradually stabilizing in the month of November.

Sources of groundwater recharge in Ranchi city and the other parts of Jharkhand State is the vertical percolation of rain water. Although city experiences about 1000 to 1200 mm rainfall annually, the rate of vertical percolation is hindered by the presence of highly weathered and metamorphosed rocks. The Ranchi plateau gradually slopes down towards south east into the hilly and undulating region of Singhbhum. Due to this uneven topography the rain water are lost through surface runoff resulting in less water percolation below the surface. The thin soil layer of Ranchi plateau which is becoming more thin due to weathering is gradually loosing its water retaining capacity, Moreover, present land development practices in the recharge area and natural canals or rivulets in and around the city is also reducing the natural recharge significantly. More than 40% of the rain water is lost in the form of surface runoff. The rate of decline ranges between 1m/year to 5m/year at different observation locations within the city.
The daily physiological consumption of drinking water for human varies from 1- 4 L per capita per day, depending upon the climate ( high in the summer), the kind of work a person does (a manual worker working in open sun would need to drink more water, than a person working in an air-conditioned office), and social habits. If we calculate total consumption of water it increases up to 40 L per capita per day especially in the country like India . Seeing the population of Ranchi, i.e. 846454 we can easily calculate average consumption of water in Ranchi city for domestic purpose per day. It is 33858160 L per day and it is increasing many fold every year. If we add the water being used in construction of houses, malls, buildings the figure will be more. As Ranchi is becoming one of the important business center in Eastern India there is a rampant increase in construction and expansion of city. Due to inadequate water supply from the dams, dependency on ground water is increasing. Over pressed zones are Upper Bazar, Main Road, Ratu Road, Chutia, Hindhpirhi, Circular Road, Burdwan Compound, Lalpur and Harmu Road.

Long term large-scale abstraction of ground water have deleterious effects on water quality, resources and ecology over a wide area.

Water quality deterioration due to overexploitation can take place in a number of ways. Depression in ground water level may result in reversal in flow directions and restrict ground water circulation. Restricted ground water circulation favours mineralization and thus increases the total dissolved solids (TDS) in the ground water. The results of ground water analysis indicate that fluoride is distributed heterogeneously in ground water of the city. Fluoride in high concentration is found in ground water of southern, western and southwestern zones of the Ranchi city. The water is found to be slightly acidic in nature and high in iron concentration in most of the zones.

Potential sources of contamination:
From experiences of other major cities of the world and observation made in Ranchi city, the possible sources of contaminants can be categorized as follows.

Municipal wastes:
Ranchi city is growing faster and without any proper municipal waste dumping policy, municipal waste can be seen dumped here and there in the city. Most of the by lanes in the city are chocked with municipal solid wastes. This municipal waste poses a serious threat to ground water quality. Leachate from a landfill can pollute ground water if water moves through the fill material. Possible sources of water include precipitation, surface water infiltration, percolating water from adjacent land, and ground water in contact with the fill. The problem of pollution from landfills is greatest where high rainfall and shallow water tables occur. Municipal waste, also called urban solid waste, is a waste type that includes predominantly household waste (domestic waste) with sometimes the addition of commercial wastes collected by a municipality within a given area. They are in either solid or semisolid form and generally exclude industrial hazardous wastes.

Municipal waste of Ranchi city is composed mainly of:

1.Biodegradable waste: food and kitchen waste, green waste, paper (can also be recycled).
2.Recyclable material: paper, glass, bottles, cans, metals, certain plastics, etc.
3.Inert waste: construction and demolition waste, dirt, rocks, debris.
4.Composite wastes: waste clothing, waste plastics.
5.Domestic hazardous waste (also called "household hazardous waste") & toxic waste: medication, paints, chemicals, light bulbs, fluorescent tubes, spray cans, batteries.

Municipal wastes produce toxic and carcinogenic chlorinated hydrocarbon solvents (CHSs) which have been found to contaminate ground water in many urban areas of the world. The CHSs are the components of the leachate produced at the disposal sites. Alongside with CHSs, leachate also contains higher amount of other dissolved solids which can also be potential source of ground water pollution. The concentration of CHSs in potable water is very hazardous, even at very low concentrations. Important pollutants frequently found in leachate include BOD, COD, iron, manganese, chloride, nitrate, hardness, and trace elements. Hardness, alkalinity, and total dissolved solids are often increased, while generation of gases, such as methane, carbon dioxide, ammonia, and hydrogen sulfide, are further by-products of landfills.

Polluted surface water:
Ranchi city is bounded by several small rivulets like Harmu river, Jumar river, Potpoto river, etc. These rivers are becoming sites for indiscriminate disposal of municipal, household and industrial wastes which may contaminate the city groundwater. This is particularly true for the Harmu river as the flow of the river is chocked with different household and municipal wastes. This river may pose major threat to the ground water quality.

Liquid waste:
Due to lack of proper drainage system most of the house hold liquid waste are sent in the disposal wells underground. Such disposal wells or soak pit tanks have been criticized from a health standpoint because of the potential for pollutants to be released directly into an aquifer. The problem is most critical where disposal wells are near pumping wells. Leakage from these wells can introduce high concentration of BOD, COD, nitrate, organic chemicals, and possibly bacteria into ground water.

Protection of ground water:

It is evident from the foregoing discussion that the aquifer beneath the city is getting overexploited and as consequence ground water resources are being depleted. Quality deterioration, an associated phenomena, of overexploitation, may be encountered. This quality deterioration will be relatively high in the overexploited and thickly populated areas. Once pollution has occurred, the water has to be treated at the point of abstraction. The cleanup of an aquifer is a very difficult task. It follows that every effort should be made to prevent the contamination of the ground water in the first instance. Rain water harvesting, harvesting of surface runoff and ground water recharge should be done in community level.

Sunday, March 1, 2009

Threat of Nitrate to our environment and health.

Jharkhand and Bihar is coming under threat
by
Dr. Nitish Priyadarshi

Nitrate (NO3-) is a water-soluble molecule made up of nitrogen and oxygen. It is formed
when nitrogen from ammonia or other sources combines with oxygenated water.

Nitrogenous materials are rare in the geological record; therefore, occurrence of nitrate in groundwater is an anthropogenic pollutant contributed by nitrogenous fertilizers, industrial effluents, human and animal wastes through biochemical activity of nitrifying bacteria, such as nitrosomanas and nitrobacter. The groundwater resources contaminated with high level of nitrate (greater than 45 mg/l) are an environmental hazard. Nitrate has been linked to agricultural activities due to excessive use of nitrate fertilizers.

The nitrate is taken up by plants during their growth and used in the synthesis of organic nitrogenous compounds. Surplus nitrate readily moves with groundwater. Under aerobic conditions, it percolates in large quantities into the aquifer because of the small extent to which degradation or denitrification occurs. Under anaerobic conditions, nitrate may be denitrified or degraded almost completely to nitrogen.

In surface water, nitrification and denitrification may also occur, depending on the temperature and pH. The uptake of nitrate by plants, however, is responsible for most of the nitrate reduction in surface water.

Concentrations of nitrate in rainwater of up to 5 mg/litre have been observed in industrial areas. In rural areas, concentrations are somewhat lower.

Nitrogen compounds are formed in the air by lightning or discharged into it from industrial processes, motor vehicles, and intensive agriculture. These are removed by wet and dry deposition.

Air pollution appears to be a minor source. In general, vegetables will be the main source of nitrate intake when levels in drinking water are below 10 mg/litre. When levels in drinking water exceed 50 mg/litre, drinking water will be the major source of total nitrate intake, especially for bottle-fed infants. In the Netherlands, the average population exposure is approximately 140 mg of nitrate per day(including the nitrate in drinking water).

Vegetables and cured meat are in general the main sources of nitrate and nitrite in the diet, but small amounts may be present in fish and dairy products. Most vegetables and fruits contain 200-2500 mg of nitrate per kg. The nitrate content of vegetables can be affected by the processing of the food, the use of fertilizers, and growing conditions. Vegetables such as beetroot, lettuce, radish, and spinach often contain concentrations above 2500 mg/kg, especially when they are cultivated in greenhouse.

The nitrate concentration in surface water is normally low (0-18 mg/litre), but can reach high levels as a result of agricultural run-off, refuse dump runoff, or contamination with human or animal wastes. The concentration often fluctuates with season and may increase when the river is fed by nitrate-rich aquifers. Nitrate concentrations have gradually increased in many European countries in the last few decades and have sometimes doubled over the past 20 years. In the United Kingdom, for example, an average annual increase of 0.7 mg/litre has been observed in some rivers.
The natural nitrate concentration in groundwater under aerobic conditions is few milligrams per litre and depends strongly on soil type and on the geological situation. In the USA, naturally occurring levels do not exceed 4-9 mg/litre for nitrate.

Several researches in India have reported nitrate incidence of groundwater related to different sources, such as leaching of organic and inorganic fertilizers from agricultural land by infiltration and percolation of rainwater, irrigation water, animal waste, leakage from sewers and by subsurface flow from up gradient areas.

Somasundram et al. (1993) reported nitrate concentrations ranging from 12 to 999 mg/litre in Madras (now Chennai) urban area, and found that source of nitrate concentrations are due to sewage effluents. In Varanasi area of Uttar Pradesh in India, high nitrate concentrations are due to the direct leaching of domestic sewage effluents.

Nitrate is high in groundwater in some pockets of Jharkhand State. Concentration varies from less than one ppm to 100 ppm. In some parts of Godda the concentration level has reached up to 168ppm. In few parts of Sisai area, near the capital of Jharkhand State the concentration is above 100ppm.

Ranchi city is coming under the threat of nitrate poisoning as city is becoming the dumping ground of the municipal wastes and household wastes. At present the concentration of nitrate has reached threshold level in groundwater of Ranchi city but it may increase in summer season because low level of groundwater increases the concentration of metals.

The accumulation of high nitrate in cracks, fissures in the hard rocks of the Jharkhand State, is obvious due to the relatively thin soil cover and occurrence of groundwater at shallower depth, pollutants find their way to the groundwater body. Other than anthropogenic sources metamorphic rocks present in Jharkhand Plateau can be the other source of nitrate to ground water because nitrogen is found in the metamorphic rocks.

In Bihar State other than Rafiganj and Bhagalpur area concentration of nitrate in groundwater is below toxic level. In Rafiganj the concentration of nitrate varies from 100 ppm (parts per million) to 300ppm. Whereas in Bhagalpur it varies from 90 to 160 ppm. In some parts of Motihari district the concentration of nitrate has reached up to the level of 155 ppm. In Valmiki Nagar few places have been identified where the concentration of nitrate has crossed the toxic level.

Health Effects:

The primary health effect from high nitrate levels is methemoglobinemia which affects infants up to 6 months of age and can ultimately result in death. The condition is also called "blue baby syndrome" because the skin appears blue-gray or lavender in color. This color change is caused by a lack of oxygen in the blood. . Bacteria that live in the digestive tracts of newborn babies convert nitrate to nitrite (NO2). Nitrite then reacts with hemoglobin, which carries oxygen in blood, to form methemoglobin. Infants suffering from "blue baby syndrome" need immediate medical care because the condition can lead to coma and death if it is not treated promptly.
Within several months after birth, the increasing level of hydrochloric acid in a baby's stomach kills most of the bacteria which convert nitrate to nitrite. By the age of six months, the digestive system is fully developed, and the risk of nitrate-induced methemoglobinemia is greatly reduced.

Increased mortality rates are recorded from gastric and prostate cancer with increasing exposures to nitrates in the drinking water as found in Spain. A cluster of spontaneous abortions was identified in Indiana among women consuming nitrate contaminated well waters. Some scientific studies have found evidence suggesting that women who drink nitrate-contaminated water during pregnancy are more likely to have babies with birth defects. Nitrate ingested by the mother may also lower the amount of oxygen available to the fetus.

The toxicity of nitrate to humans is thought to be solely the consequence of its reduction to nitrite. The major biological effect of nitrite in humans is its involvement in the oxidation of normal haemoglobin to methaemoglobin, which is unable to transport oxygen to the tissues. The reduced oxygen transport becomes clinically manifest when methaemoglobin concentrations reach 10% of that of haemoglobin and above. The haemoglobin of young infants is more susceptible to methaemoglobin formation than that of older children and adults. Other groups especially susceptible to methaemoglobin formation include pregnant women and people deficient in glucose-6-phosphate dehydrogenase or methaemoglobin reductase.

People who have heart or lung disease, certain inherited enzyme defects, or cancer may be more sensitive to the toxic effects of nitrate than others. In addition, some experts believe that long-term ingestion of water high in nitrate may increase the risk of certain types of cancer.

References:
Grant, W., Steele, G., Isiorho, S.A. 1996. Spontaneous abortions possibly related to ingestion of nitrate-contaminated well water-LaGrange County, Indiana,1991-1994. Morb. Mortal Wkly Rep., v.45, pp 569-572.

Guidelines for drinking-water quality 1999. Health criteria and other supporting information. World Health Organization, Geneva, 2nd edition, v.2.


Raju, N.J., Prahlad, R.Dey,S. 2009. Groundwater quality in the Lower Varuna River Basin, Varanasi District, Uttar Pradesh. Jr. of Geological society of India, v.73 (2) pp. 178-192.

Somasundaram, M.V., Ravindran, G., Tellam, J.H. 1993. Groundwater pollution of the Madras urban aquifer, India. Groundwater,v.31 (1) pp 4-12.


http://dnr.wi.gov/org/water/dwg/nitrate.htm
http://www.bae.ncsu.edu/programs/extension/publicat/wqwm/ag473_4.html